Tuning the reactivity of energetic nanoparticles by creation of a core-shell nanostructure.

نویسندگان

  • A Prakash
  • A V McCormick
  • M R Zachariah
چکیده

This article presents a novel method for tuning the reactivity of nanoenergetic materials by coating a strong oxidizer nanoparticle (potassium permanganate; approximately 150 nm) with a layer of a relatively mild oxidizer (iron oxide). The measured reactivity for a nano-Al/composite oxidizer could be varied by more than a factor of 10, as measured by the pressurization rate in a closed vessel (psl/micros), by changing the coating thickness of the iron oxide. The composite oxidizer nanoparticles were synthesized by a new aerosol approach in which the nonwetting interaction between iron oxide and molten potassium permanganate aids the phase segregation of a nanocomposite droplet into a core-shell structure.

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عنوان ژورنال:
  • Nano letters

دوره 5 7  شماره 

صفحات  -

تاریخ انتشار 2005